Pre-heat oven to 350 degrees and line a 12-cavity cupcake tin with papers.
In the bowl of an electric mixer or in a large bowl with a hand mixer, cream butter and sugar together until light and fluff, about 2-3 minutes. Add egg and mix to combine.
In a separate bowl, whisk together the flour, cocoa powder, baking soda, and salt.
Mix dry ingredients into wet ingredients, alternating with milk, until just blended, taking care not to over-mix.
With a spatula, stir in warm water and vodka, until batter is just combined.
Fill cupcake tins lined with cupcake papers ¾ way full of batter and bake for 18-20 minutes, until toothpick inserted into the center comes out clean.
Cool cupcakes in pan for a few minutes before removing to wire racks to cool completely.
Once cupcakes are cool, core out the center using either a cupcake corer or a knife. Fill the inside of the cupcake with marshmallow fluff.
Frost cupcakes and top with a Hershey Bar "pip."